湖北徐家山锑矿床铅同位素组成与成矿物质来源探讨   总被引：5，自引：0，他引：5  

沈能平  彭建堂  袁顺达  张东亮  胡瑞忠 《矿物学报》2008,28(2):169-176

徐家山锑矿床位于湖北省通山县境内,矿体赋存于上震旦统灯影组和陡山沱组地层中.对采自该矿的辉锑矿进行了系统的铅同位素测定.结果表明,在徐家山矿区范围内存在两组明显不同的铅同位素组成:A组206Pb/204Pb为18.874～19.288,207Pb/204Pb为 15.708～15.805, 208Pb/204Pb为38.642～39.001, 为高放射性成因铅;B组以低放射性成因铅为特征,其同位素组成206Pb/204Pb为17.882～18.171,207Pb/204Pb为15.555～15.686,208Pb/204Pb为37.950～38.340.对应地,相关参数也明显不同,如单阶段模式年龄,A组为负值或极小的正值,而B组为636～392 Ma.铅同位素组成与某些相关参数(Δγ与Δβ、V1与V2)之间呈明显线性正相关关系.根据铅构造模式和矿石铅同位素的Δγ-Δβ成因分类图解等综合分析,A组辉锑矿的铅主要来源于赋矿围岩--震旦系海相碳酸盐岩,B组主要来源于赋矿围岩的下伏基底碎屑岩--中元古界冷家溪群浅变质岩系.研究结果不支持前人沉积-改造成因的观点,成矿物质是多来源的,部分成矿物质来自基底地层.  相似文献   

贵州省册亨县百地金矿地质特征及找矿前景   总被引：3，自引：2，他引：1  

朱光荣  毛应江  季国松 《贵州地质》2008,25(3)

将册亨县百地金矿矿区划分为3个矿段,并简要描述各矿段(体)地质特征及取得的勘查进展情况。初步预测各矿体找矿前景及资源潜力。  相似文献   

贵州晴隆大厂晚二叠世初期河流相沉积特征——兼论与上下地层接触关系     

李明道 《贵州地质》2008,25(3)

晚二叠世初期,在晴隆大厂一带,以"大厂层"为基底的山间盆地中,形成了一条自北东流向南西的规模较大的曲流河。该河流微相发育,其沉积物包括河道砾岩、边滩砂屑岩和洪泛平原泥质岩等。这套沉积地层上与上二叠统峨眉山玄武岩下与"大厂层"或局部与中二叠统茅口组接触。此乃峨眉地幔隆起边缘的沉积效应。  相似文献   

浙江西沪港重金属铜的配位容量和形态分析   总被引：3，自引：2，他引：3       下载免费PDF全文

吕海燕  王正方  傅和芳  冯旭文 《海洋学报》2003,25(3):47-52

根据2000年6月10～14日在浙江省西沪港采集的海水样品,利用AA-800石墨炉原子吸收分光光度技术和阳极溶出伏安法测定样品中重金属铜的含量,获得铜在海水中受不同的有机配体控制.不同粒级的铜表观配位容量表明西沪港海水过孔径1.00μm微孔膜的(ACuCC)较高,为144.4nmol/dm3;过0.40和0.20μm滤膜的(ACuCC)分别为103.0和102nmol/dm3;铜的有机配体条件稳定常数的对数值在7.25～9.14之间.铜的总量为21.72nmol/dm3.铜全部为稳定溶解态,其中pH2酸溶态占95.0%,强有机结合态占5.0%.溶解态铜中有机结合态占过滤海水中总铜的61.6%.  相似文献   

Sensitivity to stress of the estuarine bivalve Macoma balthica from areas between the Netherlands and its southern limits (Gironde)     

H. Hummel  C. Amiard-Triquet  G. Bachelet  M. Desprez  J. Marchand  B. Sylvand  J.C. Amiard  H. Rybarczyk  R.H. Bogaards  J. Sinke  Y. De Wit  L. De Wolf 《Journal of Sea Research》1996,35(4):315-321

Variation in the sensitivity to stress of Macoma balthica was measured in several French and Dutch estuaries. For adult and juvenile Macoma balthica exposed to copper under conditions of starvation, differences in mortality rate, condition, glycogen, burrowing rate and copper content were assessed. No significant differences were observed between adults and juveniles; the influence of treatment and origin was always evident. Animals from the most southern estuaries, Loire and Gironde, near to the species's southern limit of distribution, showed, in the field, the strongest deviations for the ecophysiological traits measured, and were in the experiments the most sensitive to stress.  相似文献   

珠江口水体中铜与悬浮颗粒物相互作用的研究     

丘耀文  王肇鼎  张正斌  刘莲生 《热带海洋学报》1995,(4)

使用无机离子交换法研究珠江口水体中铜与悬浮颗粒物的相互作用，测出钢与悬浮颗粒物相互作用的ｐＨ曲线呈Ｓ形，其分级离子交换等温线是一种新的“台阶”型；从分级离子交换理论求得分级平衡常数Ｋ１为５．０，Ｋ２为７８．１，珠江口水体中铜的表观络合容量为０．９２μｍ及其条件稳定常数为３．５×１０７。  相似文献   

南海东部海域柱样沉积物浊流沉积探讨     

章伟艳  张富元  张霄宇 《热带海洋学报》2003,22(3):36-43

利用1998年南海东部陆坡69号柱样、深海盆149号柱样、南部岛礁323号柱样沉积物的粒度、化学、古生物、矿物等鉴定分析测试资料,分析了南海东部海域发生浊流沉积的地质背景、产生浊流沉积的条件和诱发因素,进而发现南海东部浊流沉积发育,在南北陆坡及中部深海盆地均有浊流沉积层。从其出现层位看,为氧同位素2—4期,即晚更新世中晚期。从浊流沉积出现层数分析,具有自北向南浊流发生频次减弱的趋势。从浊流沉积物成分看,南海东部浊流沉积物具有多样性,北部陆坡以陆源为主,中部深海盆以陆源及火山源为主,南部岛礁以生物源为主。  相似文献   

Study on copper complexing ligand concentrations in several China’s coastal waters     

GONG Haidong  ZHANG Zhengbin  LIU Chunying  LIU Liansheng 《海洋学报(英文版)》2006,25(1):64-77

Copper complexing ligand concentrations in the Daya Bay, Qingdao coast, Jiaozhou Bay, South China Sea and Huanghe Estuary waters were determined by the anodic stripping voltammetry technique. The distribution regularity and the relationship with other parameters were discussed. The results were as follows: Copper complexing ligand concentrations of the South China Sea were a little higher than those of other sea areas, and they were apparently higher than those of the ocean. Compared with the subsurface layer (SSL) in the sea surface microlayer copper complexing ligand concentrations showed an enrichment phenomenon, of which the mechanism is similar to dissolved organic matter. The metal complexing ligand concentration profiles of the South China Sea showed that the value in the sea surface was the highest, then it decreased with depth accruing, and a higher value appeared at the bottom. Copper complexing ligand concentrations were higher than those of cadmium and lead. Ligands in each sea area exhibited a complicated property. In short, the distribution regularity of copper complexing ligand concentrations in China' s coastal waters was consistent with that of other regions in the world. Meanwhile, the positive relationship between the copper complexing ligand concentrations and biological oxygen demand, chemical oxygen demand, dissolved organic carbon, and viscosity were found clearly.  相似文献   

水成沉积与风成沉积及古土壤的磁组构特征   总被引：14，自引：2，他引：14  

张家强  李从先  丛友滋 《海洋地质与第四纪地质》1999,19(2):85-94

晚第四纪水成沉积、风成沉积、古土壤等的磁组构研究表明,不同成因的沉积物具有明显不同的磁组构特征。一般地,水成沉积的体积磁化率Ｋ受物源和水动力因素控制,Ｐ和Ｆ均＞１．０２,ｑ＜０．５;风成沉积的Ｋ受物源控制,内陆黄土的Ｋ明显高于沿海黄土及海岸风沙Ｋ,Ｐ和Ｆ均＜１．０２,ｑ的平均值＞０．５５;古土壤的Ｋ受母质沉积类型和成土环境的氧化还原条件控制,内陆古土壤的Ｋ偏高,沿海古土壤的Ｋ偏低,内陆古土壤的Ｋ远高于沿海古土壤的Ｋ,Ｐ和Ｆ均＜１．０２,ｑ的平均值在０．５左右。运用典型沉积的磁组构特征对比分析未知沉积物,可以得到未知沉积物的物源、沉积过程和环境信息。  相似文献   

Distribution of dissolved species and suspended particulate copper in an intertidal ecosystem affected by copper mine tailings in Northern Chile   总被引：1，自引：0，他引：1  

Santiago Andrade  James Moffett  Juan A. Correa   《Marine Chemistry》2006,101(3-4):203-212

The coastline near Chañaral in Northern Chile is one of the most highly Cu-contaminated zones in the world due to discharges from mining activities for more than 60 years. The speciation of Cu has been studied to determine the importance of organic complexation in highly contaminated areas, and to assess the likely physiological impacts of Cu on marine organisms. Dissolved Cu concentrations of up to 500 nM were measured, completely saturating organic ligands and leading to free Cu²⁺ concentrations in excess of 10^− 8 M. These values are higher than those reported in any other marine environment, and because they occur over an extensive area, provide a unique opportunity to study the effects of Cu on marine ecosystems and to see how Cu behaves when its speciation is predominantly inorganic. We found strong gradients in free Cu²⁺ between Chañaral and adjacent areas with lower Cu, where speciation is dominated by organic complexation. There is also a significant increase in the partitioning of Cu onto suspended particles in the contaminated areas, consistent with previous studies that showed that organic ligands stabilize Cu in the dissolved phase, whilst “excess” Cu is rapidly scavenged. Those high dissolved Cu concentrations persist in spite of solid phase partitioning and advective processes along this open-ocean coastline, suggesting that Cu inputs into the system are still very large. Measurements were made using anodic stripping voltammetry with a thin mercury film coated with Nafion, which previous workers have shown can mitigate ambiguity in the data arising from inadvertent reduction of organic complexes. Our findings suggest that this is a useful methodology for contaminated systems.  相似文献